W mass measurement in the ATLAS experiment

A precise measurement of the mass of the W boson will be essential to provide improved indirect constraints, e.g. on the Higgs boson mass. Using new methods developed for this challenging measurement, the performance expected is presented, evaluating various sources of systematic uncertainties, both of experimental and theoretical nature. The focus of this contribution will be on the expectation for the initial data taking and results will be shown for an integrated luminosity of 15 pb-1. Prospects on the total uncertainties which may be obtained with an integrated luminosity of 10 fb-1 will be given

Electroweak Physics Measurements at the LHC

Although often quoted as a discovery collider, the LHC will also allow for precise measurements. In particular, in the electroweak sector, the determination of the masses of the top quark and the W boson will benefit from high statistics and new methods

Υ\Upsilon radiative decays to light quark jets and color octet mechanism

We study radiative decays of $\Upsilon$ to light quark jets in nonrelativistic QCD by taking both the color singlet and color octet $b\bar b$ operators into consideration. The cut for quark jet energy and cut for the angle between two quark jets are introduced. The sensitivity to the soft and collinear singularities in the loop integrals are greatly reduced by these cuts. With the jet energy cut of about 1 GeV, and the jet angle cut of about $36^\circ$, the branching ratio for $\Upsilon\to\gamma q\bar q$ is found to be $8.2\times 10^{-4}$ from color singlet contributions. The color octet contributions could be much larger than that of color singlet, depending on the estimate of the color octet matrix elements. This process may provide a new test for the color octet mechanism in nonrelativistic QCD.Comment: journal version; a few references adde

Dihydroxyacetone conversion into lactic acid in an aqueous medium in the presence of metal salts: influence of the ionic thermodynamic equilibrium on the reaction performance

International audienceThe catalytic conversion of dihydroxyacetone (DHA) to lactic acid (LA) via pyruvaldehyde (PA) in aqueous media was studied using different homogeneous metal salts. A kinetic model was developed and the parameters corresponding to each reaction steps were estimated. Agreement between experiments and simulated results was excellent and the performance of the different catalysts was consistent with previous studies described in the literature. Aluminium salts, which show the best performance, were tested in a whole range of concentrations and at different pH, in order to identify the catalytically active ionic species. It was confirmed that the DHA to pyruvaldehyde (PA) dehydration step is catalyzed by both Brønsted and Lewis acids whereas the consecutive reaction of PA to LA is solely catalyzed by Lewis acids. Moreover, comparing thermodynamic analysis of the reaction media and kinetic parameters demonstrated that cationic hydroxyl-aluminium complexes [Al(OH)h] (3-h)+ formed in situ by the hydrolysis of the aluminium aqua complexes like [Al(OH2)6] 3+ are the most active Lewis acids

Atomic structure and vibrational properties of icosahedral B4_4C boron carbide

The atomic structure of icosahedral B$_4$C boron carbide is determined by comparing existing infra-red absorption and Raman diffusion measurements with the predictions of accurate {\it ab initio} lattice-dynamical calculations performed for different structural models. This allows us to unambiguously determine the location of the carbon atom within the boron icosahedron, a task presently beyond X-ray and neutron diffraction ability. By examining the inter- and intra-icosahedral contributions to the stiffness we show that, contrary to recent conjectures, intra-icosahedral bonds are harder.Comment: 9 pages including 3 figures, accepted in Physical Review Letter

Z boson transverse momentum spectrum from the lepton angular distributions

In view of recent discussions concerning the possibly limiting energy resolution systematics on the measurement of the Z boson transverse momentum distribution at hadron colliders, we propose a novel measurement method based on the angular distributions of the decay leptons. We also introduce a phenomenological parametrization of the transverse momentum distribution that adapts well to all currently available predictions, a useful tool to quantify their differences.Comment: 12 pages, 6 figure

Synthesis of Thiazolo[5,4-f]quinazolin-9(8H)-ones as Multi-Target Directed Ligands of Ser/Thr Kinases

International audienceA library of thirty novel thiazolo[5,4-f]quinazolin-9(8H)-one derivatives belonging to four series designated as 12, 13, 14 and 15 was efficiently prepared, helped by microwave-assisted technology when required. The efficient multistep synthesis of methyl 6-amino-2-cyano- benzo[d]thiazole-7-carboxylate (1) has been reinvestigated and performed on a multigram scale. The inhibitory potency of the final products against five kinases involved in Alzheimer’s disease was evaluated. This study demonstrates that some molecules of the 12 and 13 series described in this paper are particularly promising for the development of new multi-target inhibitors of kinase

Predictions for the Cosmogenic Neutrino Flux in Light of New Data from the Pierre Auger Observatory

The Pierre Auger Observatory (PAO) has measured the spectrum and composition of the ultrahigh energy cosmic rays with unprecedented precision. We use these measurements to constrain their spectrum and composition as injected from their sources and, in turn, use these results to estimate the spectrum of cosmogenic neutrinos generated in their propagation through intergalactic space. We find that the PAO measurements can be well fit if the injected cosmic rays consist entirely of nuclei with masses in the intermediate (C, N, O) to heavy (Fe, Si) range. A mixture of protons and heavier species is also acceptable but (on the basis of existing hadronic interaction models) injection of pure light nuclei (p, He) results in unacceptable fits to the new elongation rate data. The expected spectrum of cosmogenic neutrinos can vary considerably, depending on the precise spectrum and chemical composition injected from the cosmic ray sources. In the models where heavy nuclei dominate the cosmic ray spectrum and few dissociated protons exceed GZK energies, the cosmogenic neutrino flux can be suppressed by up to two orders of magnitude relative to the all-proton prediction, making its detection beyond the reach of current and planned neutrino telescopes. Other models consistent with the data, however, are proton-dominated with only a small (1-10%) admixture of heavy nuclei and predict an associated cosmogenic flux within the reach of upcoming experiments. Thus a detection or non-detection of cosmogenic neutrinos can assist in discriminating between these possibilities.Comment: 10 pages, 7 figure

Synthesis of bioactive 2-(arylamino)thiazolo[5,4-f]-quinazolin-9-ones via the Hügershoff reaction or Cu- catalyzed intramolecular C-S bond formation

International audienceA library of thirty eight novel thiazolo[5,4-f]quinazolin-9(8H)-one derivatives (series 8, 10, 14 and 17) was prepared via the Hügershoff reaction and a Cu catalyzed intramolecular C-S bond formation, helped by microwave-assisted technology when required. The efficient multistep synthesis of the key 6-amino-3-cyclopropylquinazolin-4(3H)-one (3) has been reinvestigated and performed on a multigram scale from the starting 5-nitroanthranilic acid. The inhibitory potency of the final products was evaluated against five kinases involved in Alzheimer’s disease and showed that some molecules of the 17 series described in this paper are particularly promising for the development of novel multi-target inhibitors of kinases

Investigation of conduction band structure, electron scattering mechanisms and phase transitions in indium selenide by means of transport measurements under pressure

In this work we report on Hall effect, resistivity and thermopower measurements in n-type indium selenide at room temperature under either hydrostatic and quasi-hydrostatic pressure. Up to 40 kbar (= 4 GPa), the decrease of carrier concentration as the pressure increases is explained through the existence of a subsidiary minimum in the conduction band. This minimum shifts towards lower energies under pressure, with a pressure coefficient of about -105 meV/GPa, and its related impurity level traps electrons as it reaches the band gap and approaches the Fermi level. The pressure value at which the electron trapping starts is shown to depend on the electron concentration at ambient pressure and the dimensionality of the electron gas. At low pressures the electron mobility increases under pressure for both 3D and 2D electrons, the increase rate being higher for 2D electrons, which is shown to be coherent with previous scattering mechanisms models. The phase transition from the semiconductor layered phase to the metallic sodium cloride phase is observed as a drop in resistivity around 105 kbar, but above 40 kbar a sharp nonreversible increase of the carrier concentration is observed, which is attributed to the formation of donor defects as precursors of the phase transition.Comment: 18 pages, Latex, 10 postscript figure